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Beilstein J. Org. Chem. 2016, 12, 2620–2626, doi:10.3762/bjoc.12.258
Graphical Abstract
Scheme 1: L-Proline-promoted stereoselective aldol reaction in DES.
Figure 1: Experimental set-up I: test tube (d = 0.5 cm); flow 1 mL/min; DES (1.5 mL); L-proline/DES = 130 mg/...
Scheme 2: Aldol reaction under continuous flow conditions in DESs.
Beilstein J. Org. Chem. 2013, 9, 633–640, doi:10.3762/bjoc.9.71
Figure 1: Catalysts of types A–D.
Figure 2: Catalysts of types E–H.
Figure 3: Proposed approach in this work.
Scheme 1: Stereoselective reduction of ketones.
Figure 4: Catalysts synthesized and studied in this work.
Figure 5: Calculated transition states for catalyst 6.